Catechism Section 1131
"The sacraments are efficacious signs of grace, instituted by Christ and entrusted to the Church, by which divine life is dispensed to us. The visible rites by which the sacraments are celebrated signify and make present the graces proper to each sacrament."
Note that the Catholic Church does not state that the Sacraments are the only way that these graces are bestowed upon us.